涉密矢量数字地图中敏感要素几何信息量的测度方法

涉密矢量数字地图中敏感要素几何信息的定量测度,是实现定量化密级评定的基础和前提。如何进行敏感要素几何信息量的计算,目前尚缺乏相关研究。在现有地图信息论研究成果的基础上,论文主要开展了3方面的研究工作：首先,从地理对象的敏感性入手,探讨了地图要素敏感性的定义与要素集合的敏感性表征指标;然后,基于任意发生元的Voronoi构建方法,实现了对点要素集、线要素集、部分覆盖面要素集及综合要素集的信息单元自动化剖分;最后,基于长度系数、面积系数和角度系数,提出了线、面要素图形复杂度的计算方法,并在此基础上形成了涉密矢量数字地图中敏感几何信息量的测度方法。实验表明,该方法的计算结果遵循了信息量的非负性、连续性、可加性等特点,较为合理地反映了相关因素（地图比例尺、要素空间分布、要素图形复杂度、要素敏感系数等）对计算结果的影响。相关成果将支持矢量数字地图的定量化密级评定,并有助于完善地理信息安全监管的理论和方法体系。     

Theoretical Prediction of Gibbs Free Energies of Formation for Crystalline α-MOOH and α-M2O3 Based on a Linear Free-Energy Relationship

In the present study, the modified Sverjensky–Molling equation, derived from a linear-free energy relationship, is used to predict the Gibbs free energies of formation of crystalline phases of α-MOOH (with a goethite structure) and α-M2O3 (with a hematite structure) from the known thermodynamic properties of the corresponding aqueous trivalent cations (M3+). The modified equation is expressed as ΔG0f,MVX=aMVXΔG0n,M3++bMVX+βMVXγM3+, where the coefficients aMVX, bMVX, and βMVX characterize a particular structural family of MvX (M is a trivalent cation [M3+] and X represents the remainder of the composition of solid); γ3+ is the ionic radius of trivalent cations (M3+); ΔG0f,MVX is the standard Gibbs free energy of formation of MvX; and ΔG0n,M3+ is the non-solvation energy of trivalent cations (M3+). By fitting the equation to the known experimental thermodynamic data, the coefficients for the goethite family (α-MOOH) are aMVX=0.8838, bMVX=?424.4431 (kcal/mol), and βMVX=115 (kcal/mol.?), while the coefficients for the hematite family (α-M2O3) are aMVX=1.7468, bMVX=?814.9573 (kcal/mol), and βMVX=278 (kcal/mol.?). The constrained relationship can be used to predict the standard Gibbs free energies of formation of crystalline phases and fictive phases (i.e. phases that are thermodynamically unstable and do not occur at standard conditions) within the isostructural families of goethite (α-MOOH) and hematite (α-M2O3) if the standard Gibbs free energies of formation of the trivalent cations are known.     

鞍本地区早前寒武纪地质体铅同位素组成及铀源条件定量计算方法研究

本文对比了鞍本地区前寒武纪铅-锌-银矿区和铀矿区的硫化物矿石和花岗岩长石Pb同位素组成,分别用矿石铅二阶段普通铅法、铅构造模式图解和全岩铅同位素组成三阶段拟合法计算了年龄和全岩原始铀含量。结果表明,矿石铅和长石铅模式年龄约为2000 Ma,在铅构造模式图上投影于2000~1600 Ma间,花岗岩和辽河群全岩拟合年龄为2000~1800 Ma;铅同位素组成显示铅-锌-银来自早元古代辽河群地层,连山关地区明显为放射性成因Pb同位素组成,源于富铀花岗岩。连山关矿石铅年龄和全岩三阶段年龄与该区铀矿床沥青铀矿的年龄基本一致;花岗岩原始铀的得失计算表明,该地区不同地质体均经历了约2000~1800 Ma花岗岩重熔改造,花岗质岩石发生了铀的丢失,是连山关地区铀矿的主要来源。     

凉山瓦西乡南红玉中的赤铁矿包裹体特征与成因

瓦西乡产出的南红玉中的红色点状及火焰纹典型包裹体分别是石英中的红色球粒与红色管状包裹体。鏡下及扫描电镜(SEM)研究,红色球粒分布在"三色"层水晶的菱面体单形晶面的间歇层面中,由红色核、黑色壳和红色表层组成;火焰纹管状包裹体主要出现在条带水晶中,管的方向垂直水晶的菱面体晶面,管的内壁呈黑色,外壳为红色。其球粒表层或管外壳的颜色、厚度及透光性则直接影响南红的颜色质量与润泽性。研究表明,球粒状和火焰状包裹体主要由片状、鳞片状或板片状赤铁矿组成;球粒圈层中的赤铁矿晶体c轴取向呈规律变化,可能与其V2O5含量有关。据水晶晶体中的球粒、管及共生矿物绿帘石、黄铜矿包裹体的红外光谱(IR)及流体包裹体均一法测温与激光拉曼(LRS)分析,球或管的赤铁矿属含有机质的低温热液(约160℃)成因,成矿溶液中的有机质也是促使铁氧化物凝聚形成具不同圈层结构的红色球粒与管的主要原因。有机质可能来自下二叠统茅口组碳酸盐。     

The Energy Relationship between Ions and Soil Particles based on Wien Effect and Its Application in Soil Science

The interaction between ions and soil particles plays an important role in the mobilization and bioavailability of ions in soils, which is one of the main research areas of soil chemistry. The new method based on suspension Wien effect has been developed recently to determine the binding energy and adsorption energy between ions and soil particles. Compared with other methods on the basis of adsorption isotherm or ions activity, Wien effect method has more advantages including convenience and direct measurement. The term suspension Wien effect refers to the increase of electrical conductivity of suspension with increasing applied electrical field. In this review paper, we introduced the fundamentals of suspension Wien effect, the apparatus about the Wien effect measurement, and along with demonstrating their application to quantifying the particles-ions interactions for several systems of soils. Our studies indicated that divalent cations have larger binding energies and adsorption energies on soil particles than monovalent because of the electrostatic interaction. However, few studies about the interaction between Cr³⁺ and La³⁺ on soil particles showed that the binding energy and adsorption energy of trivalent cations are lower than those of divalent cations because of hydrolysis. Soil properties such as soil organic matter, soil pH, and iron oxides significantly affected the binding energy and adsorption energy of ions. Our results deepened our understanding about the non specific adsorption of ions in soil chemistry, and enlarged the research area of soil chemistry in fundamental and methodology.     

基于GIS建立空间图形数据库的方法

数字化空间图形数据库是空间图形及其属性数据库的统，建立数字化空间图形数据库是一个非常繁琐的工程。而先建立空间图形库，然后进行各图元属性ID号排序，再“根据参数赋属性”建立完整的空间图形数据库，会取得事半功倍的效果。     

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AIMS AND SCOPE
Atmospheric and Oceanic Science Letters （AOSL） publishes short research letters on all disciplines of the atmosphere sciences and physical oceanography. Contributions from all over the world are welcome.     

关于高精度航空磁测中的磁补偿原理及补偿效果评价的探讨

对于高精度航空磁测来说,飞机磁干扰必须有效的消除,其方法是补偿飞行。补偿效果的好坏直接影响到物探飞行数据的质量,所以有必要采用一些量化指标对磁补偿的效果进行评价,从而对补偿飞行的质量进行有效地控制。这里介绍了飞机磁干扰场的补偿原理及两种评价补偿效果的指标:品质因数(FOM值)和标准差(σc),采用了这两个量化指标对磁补偿的效果进行评价,就能对补偿飞行的质量进行有效的控制。     

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正1 AIM AND SCOPE GEOSCIENCE FRONTIERS(GSF) is a bi-monthly international journal that publishes in English high quality original research articles and timely reviews in interdisciplinary fields of Earth and Planetary Sciences.GSF aims to bridge innovative,provocative and challenging concepts and models related to various fields of research including petrology and geochemistry in understanding lithospheric architecture